Diffusive two-dimensional spreading of a polymer

نویسندگان

  • Uwe Albrecht
  • Achim Otto
  • Paul Leiderer
چکیده

We have measured the thickness profiles of ultrasmall (picoliter volume) droplets of polyd~mcthvls~loxane during thelr spreading on a silver surface at centra! thicknesses below one monolayer. The resulting prufile shapes can he approximated well by shperical caps, and the diffusion dynamics are q u ~ t e difterent from those expected for mintlike particles. Thc cxpcrimental data are in remarkable agreement with Monte Carln simulations or a spreading two-dirnenr~onal polymer lattice-gas, which are performed using the bond fluctuation method.

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تاریخ انتشار 2005